Other countries are following suit and driving the market toward hfc free. The hfc refrigerants are considered as one of the six target greenhouse. Alternatives for hcfc and hfc refrigerants halogen free refrigerants. Products that normally contain ozone depleting substances should be replaced with functionally similar products that contain non ozone depleting substances. Performance assessment of vapor compression systems.
Inventories and projections of ozone depleting and. The ozone depletion potential odprh of a gas rh is the relative. In the december 20, 2011 snap rule, epas analysis of environmental impacts for these refrigerant substitutes discussed four types of environmental risks. Non ozone depleting substances ods do not deplete the earths protective ozone layer. For this proposal, epas discussion of potential environmental.
The regulation for the management of high global warming potential refrigerants for stationary sources carb. This refrigerant offers ultralow global warming potential gwp ozone depletion potential odp and is not. Chemical molecular boiling point ozone depletion potential global warming potential refrigerants formula weight14 oc14 odp15 gwp15 r32 ch2f2 52 51. This is a new refrigerant with zero ozone depletion potential and low global warming potential. Refrigerant reclaim australia michael bennett and csiro dr paul fraser. Inventories and projections of ozone depleting and synthetic. This refrigerant offers ultralow global warming potential gwp ozone depletion level odp and is not subject to the hydrofluorocarbon hfc phasedown required by the european unions fgas regulation. A refrigerant is a working fluid used in the refrigeration cycle of air conditioning systems and. Refrigerant selection to reduce climate impact edge buildings. Gwp global warming potential degree to which a greenhouse gas ghg traps heat in the atmosphere. The ozone depletion potential odp of a chemical compound is the relative amount of degradation to the ozone layer it can cause, with trichlorofluoromethane r11 or cfc11 being fixed at an odp of 1. Refrigerants are heavily regulated due to their toxicity, flammability and their contribution to ozone depletion and climate change. Zero ozone depletion potential replacement for r22.
Montreal protocol, an international agreement to protect the ozone layer, canada is committed to eliminating releases of odss. Therefore, tradeoffs among desired objectives are necessary to. Ozone depleting substances are the substances such as chlorofluorocarbons, halons, carbon tetrachloride, hydrofluorocarbons, etc. Other countries are following suit and driving the market toward hfcfree. May 31, 2020 each refrigerant has its own ozone depletion potential factors towards global warming on the earth.
Using the handout provided, briefly describe the major events that occurred in the area of. Hfcs were not ozone depleting but which did have global warming potentials gwps. It is commonly used as a propellant and refrigerant. Ozone depletion potential article about ozone depletion. Hfcs r4a do not contain chlorine and have no ozone depletion potential. Ozone layer protection environmental protection department. Linde strongly advocates the use of refrigerant gases with zero ozone depletion potential and fully supports the phase out of ozone depleting. As you know that i am a govt certified mountaineer and adventure guide i am a trek leader and lead expeditions and trek batches for terranova adventure. It went into effect in 1987, first targeting cfcs, then hcfcs. But the outlook for discovery or synthesis of these ideal refrigerants is extremely unlikely.
Substances with high global warming potential gwp are a key concern. However, while the ozone depletion potential odp of r4a is zero, global warming potential gwp is high gwp 1430. The odp values are from table 15 of the scientific assessment of ozone depletion, 2002, a report of the world meteorological associations global ozone research and monitoring project. A table of ozonedepleting substances shows their odps, gwps, and cas numbers. Chronology of chlorofluorocarbons and ozone chlorofluorocarbons cfcs used as refrigerants in refrigerators and air conditioners, and as aerosol propellants, have changed over the past 100 years.
Like all hcfcs, however, r22 has been shown to deplete the ozone layer. Deplete the ozone layer, article 7 of the protocol. Ozone is a gas composed of three bonded oxygen atoms o 3. Some of these changes were spurred by the harmful effects of the compounds. Energy performance of ecofriendly re170 and r510a refrigerants as alternatives to r4a in vapour compression refrigeration system. Pdf selection of environmentfriendly refrigerants and. Pdf this paper presents natural refrigerants as the ideal. Aircooled chillers with high speed centrifugal compressors. Global warming potential ozone depletion potential coefficient of performance the outlook for discovery or synthesis of ideal refrigerants is extremely unlikely. Hcfcs have less ozone depleting potential than cfcs and have been useful as an interim alternative to bridge the transition to ods elimination. American society of heating, refrigerating and air. Gwps including indirect effects of ozone depletion have been estimated fo r a variety of halocarbons cfcs, halons, hcfcs, etc. The gwp scale is standardized to carbon dioxide, where the refrigerants value is the multiple of the heat that would be absorbed by the same mass of carbon dioxide over a period of time.
Cfc 11, or r11 has the maximum potential amongst chlorocarbons because of the. Ozone depletion potentials and global warming potentials the effectiveness of bromine compared with chlorine on a peratom basis for global ozone depletion, typi cally referred to as. The danfoss turbocor portfolio of oilfree compressors. Ozonedepleting substances ozone layer protection us epa. Refrigerants are typically evaluated on both their global warming potential gwp and ozone depletion potential. Odp ozone depletion potential degree to which a substance can degrade the ozone layer. The current generation of refrigerants, hydrofluorocarbons hfcs, have zero ozone depletion potential. In the refrigerant sector two mature technologies, fluorinated refrigerants hfcs with their high global warming potential as well as environmentally friendly natural refriger. Other substitute refrigerants are available with low gwp. Reduce refrigerant leak to 10% per year, refrigerant gwp by 50%, and reduce charge by 65% 40% indirect warming impact energy consumption. Responsibility for the content and conclusions of the report rest with burnbank consulting pty.
Phaseout of class ii ozonedepleting substances us epa. Refrigerants for commercial refrigeration applications rsd. Refrigeration, air conditioning and heat pumps cfcs. R410a, sold under the trademarked names az20, ecofluor r410, forane 410a, genetron r410a, puron, and suva 410a, is a zeotropic but nearazeotropic mixture of difluoromethane ch 2 f 2, called r32 and pentafluoroethane chf 2 cf 3, called r125 that is used as a refrigerant in air conditioning applications. Refrigerant and materials selection to mitigate climate impact. A fourth generation refrigerant would ideally be efficient, nonflammable and non toxic with good stability, no global warming potential gwp and no ozone depletion potential odp.
The tth model is compatible with r4a and nonflammable r5a while the tgh model uses next generation refrigerant hfo1234ze. Pdf scientists understanding of ozone and chlorofluorocarbons. A refrigerant is a working fluid used in the refrigeration cycle of air conditioning systems and heat pumps where in most cases they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerant monitor began the fulltime manufacture of the first polyiso roof insulation with zero ozone depletion potential odp and zero global warming potential gwp at one of its seven plants. Pdf comparative analysis of performance of three ozone. Historically, chlorofluorocarbons cfcs were used extensively as refrigerants in the air conditioning and refrigeration industries.
Tradeoffs among desired objectives are necessary to achieve balanced solutions4 4 calm, james m. Chlorodifluoromethane r22, for example, has an odp of 0. Cfcs were replaced with hcfcs, which have lower ozone depletion potential odp, or with. Indias top 10 largest and safest trekking company, hence it is my responsibility to. Refrigerants are typically evaluated on both their global warming potential gwp and ozone depletion potential odp.
Pdf experimental investigation on the performance of air. Production of hcfcs with the highest odps are being phased out first, followed by other hcfcs. Specifically, this paper seeks to help readers pursue a more energyefficient future by providing detailed information on lowgwp alternative refrigerants, explaining current and future policies that will impact this sector, and providing additional. The computed odp values for hcfc refrigerants were very low on the order of 0. Pdf selection of environmentfriendly refrigerants and the. Refrigerants regulated under the refrigerant management program rmp include any refrigerant that is an ozone depleting substance ods as defined in title 40 of the code of federal regulation, part 82, and any compound with a global warming potential gwp value equal to or greater than 150 according to the gwps specified in ipccs fourth assessment report of 2007. The usage of these refrigerants concerns about environmental issues like global warming potential and ozone depletion.
Federal register protection of stratospheric ozone. Mar 10, 2017 include cfcs, halons, carbon tetrachloride, methyl chloroform and other chemicals with an ozone depletion potential of 0. A refrigerant is a fluid that is used for heat transfer in a cooling system. For each ods, this page provides the compounds atmospheric lifetime, ozone depletion potential ozone depletion potentiala number that refers to the amount of ozone depletion caused by a substance. The consideration of these refrigerants continues to come under question due to the environmental concerns caused from ozone depleting potential odp, global warming potential gwp, energy efficiency, total equivalent warming impact tewi and life cycle climate performance lccp. Hcfcs are assigned ozone depletion potentials odp depending on their potential specified relative to cfc11 to cause ozone depletion in the stratosphere see table 1. Ozone depletion potential an overview sciencedirect topics. Chris downton, energy strategies, assisted in providing information on halons, methyl chloroform, and carbon tetrachloride. Class ii odss are listed in section 602 of the caa, and comprise all hcfcs which have an ozone depletion potential of less than 0.
Chemical molecular boiling point ozone depletion potential global warming potential refrigerants formula weight14 oc. The odp is the ratio of the impact on ozone of a chemical compared to the impact of a similar mass of cfc11. Feb 01, 2017 hcfc, and other synthetic refrigerants. Hfcs which have zero ozone depletion potential odp but their global warming potential gwp is relatively high 6. Through the montreal protocol, the world developed an unprecedented response for the environmental problem of stratospheric ozone depletion by phasing out the manufacture and the eventual use of ozone depleting refrigerants. Chapte r ozone depletion potentials, global warming. The environmental challenge for over twenty years, the hydrochlorofluorocarbon hcfc r22 has been an extremely useful refrigerant gas across a wide range of air conditioning and refrigeration applications. Jul 09, 2014 based on this still conservative but more probable assessment of refrigerant use, we found that even if all the refrigerant in appliances in enduses addressed in this proposed rule were to be emitted, there would be a worstcase impact of 0. Hcfcs were used as a replacement for cfcs because their odp is up to 20 times lower.
Incorporating product design into the development of new. Chlorine and fluorine atoms are not present in the refrigerant is referred to as the hydrocarbons hc, fluorine atom in the molecule of refrigerant makes them physiologically more favorable and chlorine atom leads to odp. Refrigeration, air conditioning and heat pumps cfcs and. The additional primary medium which absorbs and removes heat and global warming hwang et al. Following is the list of some main ozone depleting substances and the sources from where they are released. Due to this reason, some restrictions have already been placed on their use in europe. Jan 28, 2009 consequences of the refrigerants being used and the systems which use them. R410a, for example, is often substituted, but has a gwp of 1725. Montreal protocol, the odp of refrigerants should be zero, i. Fd dryers use cfc free refrigerants r4a and r410a with an ozone depletion potential odp of zero.
Refrigerants are regulated as hazardous materials by the us epa and carb, due to their ozone depleting ability and powerful greenhouse gas potential. Assessment of the environmental acceptability of refrigerants by. Alternative refrigerants must replace the existing ones with fewer environmentally concerns such as low global warming potentials gwp, low ozone depletion potentials odp, low toxicity, and adequate air conditioning ac characteristics. Ozone depletion potential 0 low global warming potential gwp ozone depletion potential of a chemical is the amount of degradation to the ozone layer it can cause. Chlorodifluoromethane or difluoromonochloromethane is a hydrochlorofluorocarbon hcfc. Annex a provides a list of class i odss, and annex b provides a list. Highefficiency heat exchanger counterflow compact brazed plate or aluminum heat exchanger, with airtoair side for optimum cooling efficiency and the lowest possible pressure drop.
Halocarbon potential contributions to ozone depletion and global warming exhibit 2 provides odps for the class i and class ii odss. Aug 25, 2020 hcfcs have ozone depletion potentials odps ranging from 0. The natural refrigerant industry is expected to have a compounded annual growth rate of 8. This colorless gas is better known as hcfc22, or r22, or chclf 2. Refrigerants environmental properties physical and. The higher the number, the more damage a chemical can cause to. The net gwps of halocarbons depend strongly upon the effectiveness of each compound for ozone destruction. Experimental studies on the retrofitted r4a system indicated 5. Expansion now include zero ozone depletion potential odp and zero device global warming potential gwp 56. Hydrofluorocarbons hfcs are often substituted for r22 because of their lower ozone depletion potential, but these refrigerants often have a higher gwp. The linkage of the cfc depletion potential odp and zero global subsequently rejects that heat elsewhere. Highgwp refrigerants california air resources board.
These applications are being phased out in developed countries due to the compounds ozone depletion potential odp and high global warming potential gwp, although global use of r22. Ranking are based upon ozone depletion potential, global warming potential, and atmospheric lifetime and are achieved by applying the hasse diagram. The odp data of all ozonedepleting substances are tabulated in table 2. Ozone layer depletion odp and global warming potential gwp have become one of the most important global issues. Pdf thermodynamic analysis of actual vapour compression. Pdf refrigerant r4a properties aman kumar academia. Ozone layer depletion cause, effects, and solutions. Ozone depletion and global warming potential of thermal.
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